Product ID:132010-00650, TOLUENE
MSDS Date:07/01/1985
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CLQBM

Emergency Phone: 713-656-3424

Info Phone: 713-656-2443; 713-656-5949

Preparer: NOT PROVIDED

Cage: UO148

Telephone: 713-656-2443; 713-656-5949

Cage: UO148

TOLUENE

CAS: 108-88-3

RTECS: XS5250000

OSHA PEL see Table Z-2

ACGIH TLV: 188 MG/M3;50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:NATURE OF HAZARD: PROLONGED OR
REPEATED SKIN CONTACT WITH THIS PRODUCT TENDS TO REMOVE SKIN OILS
POSSIBLY LEADING TO IRRITATION AND DERMITITIS. PRODUCT CONTACTING
THE EYES MAY CAUSE EYE IRRITATION. TH IS PRODUCT HAS A LOW ORDER OF
ACUTE ORAL TOXICITY, BUT MINUTE AMOUNTS ASPIRATED INTO THE LUNGS
DURING INGESTION MAY CAUSE SEVERE PULMONARY INJURY OR DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HIGH VAPOR CONCENTRATIONS (GREATER THAN
APPROXIMATELY 1000PPM) ARE IRRITATING TO THE EYES AND THE
RESPIRATORY TRACT, MAY CAUSE HEADACHES AND DIZZINESS, ARE
ANESTHETIC, AND MAY HAVE OTHER CENTRAL NERVO US SYSTEM EFFECTS.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:EYE: IF SPLASHED INTO THE EYES, FLUSH WITH CLEAR WATER FOR 15
MINUTES OR UNTIL IRRITATION SUBSIDES. IF IRRITATION PERSISTS, CALL
PHYSICIAN. SKIN: REMOVE ANY CONTAMINATED CLOTHING AND WASH SKIN
THOROUG HLY WITH SOAP AND WATER. INHALATION: IF OVERCOME BY VAPOR,
REMOVE FROM EXPOSURE AND CALL PHYSICIAN IMMEDIATELY. IF BREATHING
IS IRREGULAR OR HAS STOPPED START RESUSCITATION, ADMINISTER OXYGEN,
IF AVAI LABLE. INGESSTION: IF INGESTED, DO NOT INDUCE VOMITING,
CALL PHYSICIAN IMMEDIATELY.

Flash Point Method:TCC
Flash Point:=7.2C, 45.F
MINIMUM
Autoignition Temp:>537.8C, 1000.F
Lower Limits:1%
Upper Limits:7.1%
Extinguishing Media:USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER MAY
BE INEFFECTIVE BUT WATER SHOULD BE USED TO KEEP FIRE-EXPOSED
CONTIANERS COOL.
Fire Fighting Procedures:IF A LEAK OR SPILL HAS IGNITED, USE WATER
SPRAY TO DISPERSE THE VAPORS AND TO PROTECT MEN ATTEMPTING TO STOP
A LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM
EXPOSURES. MINIMIZE BREATHING GAS /VAPOR/FUMES OR DECOMPOSITION
PRODUCTS. USE SUPPLIED-AIR BREATHING EQUIPMENT FOR ENCLOSED OR
CONFINED SPACES, AS NEEDED.
Unusual Fire/Explosion Hazard:"EMPTY" CONTAINERS RETAIN RESIDUE (LIQUID
AND/OR VAPOR) AND CAN BE DANGEROUS. DO NOT EXPOSE SUCH CONTAINERS
TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION; THEY MAY
EXPLODE AND CAUSE INJURY OR DE ATH.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. KEEP PEOPLE
AWAY. RECOVER FREE PRODUCT. ADD SAND, EARTH OR OTHER SUITABLE
ABSORBENT TO SPILL AREA. MINIMIZE BREATHING VAPORS AND SKIN
CONTACT. VENTILATE CONFINED SPACES . KEEP OUT OF SEWERS AND
WATERCOURSES BY DIKING/IMPOUNDING. ADVISE AUTHORITIES IF PRODUCT
HAS ENTERED OR MAY ENTER SEWERS, WATERCOURSES/ LAND. ASSURE
CONFORMITY WITH REGULATIONS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:USE EXPLOSION PROOF EQUIPMENT. NO
SMOKING OR OPEN LIGHTS. DO NOT HANDLE OR STORE NEAR HEAT, SPARKS,
FLAME OR STRONG OXIDANTS. TO PREVENT FIRE OR EXPLOSION RISK FROM
STATIC ACCUMULATION AND DISCHARGE, EFFECTVELY GROUND PRODUCT
TRANSFER SYSTEM.
Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. MINIMIZE
BREATHING VAPOR OR MIST. AVOID PROLONGED OR REPEATED CONTACT WITH
SKIN. PRODUCT IS READILY REMOVED FROM SKIN BY WATERLESS HAND
CLEANERS FOLLOWED BY WAS HING THOROUGHLY WITH SOAP AND WATER.

Respiratory Protection:USE AIR-SUPPLIED RESPIRATORY PROTECTION IN
CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:PROVIDE >60 FEET PER MINUTE HOOD FACE VELOCITY.USE
EXPLOSION-PROOF EQUIPMENT SUFFICIENT TO PREVENT EXCEEDING
RECOMMENDED EXPOSURE LIMITS. NO SMOKING
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:SPLASH GOGGLES OR FACE SHIELD
Other Protective Equipment:CHEMICAL RESISTANT APRON OR OTHER IMPERVIOUS
CLOTHING TO AVOID CONTAMINATING CLOTHING WHICH COULD RESULT IN
PROLONGED OR REPEATED SKIN CONTACT.
Work Hygienic Practices:MINIMIZE BREATHING VAPOR OR MIST. AVOID
PROLONGED OR REPEATED CONTACT WITH SKIN. REMOVE CONTAMINATED
CLOTHING; LAUNDER OR DRY-CLEAN BEFORE REUSE. REMOVE CONTAMINATED
SHOES AND THOROUGHLY CLEAN AND DRY.
Supplemental Safety and Health
CLEANSE SKIN THOROUGHLY AFTER CONTACT, BEFORE BREAKS AND MEALS, AND AT
END OF WORK PERIOD. PRODUCT IS READILY REMOVED FROM SKIN BY
WATERLESS HAND CLEANERS FOLLOWED BY WASHING THOROUGHLY WITH SOAP
AND WATER.

HCC:F2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:110.2-111.0C
Melt/Freeze Pt:<-17.6C, 0.F
M.P/F.P Text:POUR
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:~54MMHG @25C
Vapor Density:~3.2
Spec Gravity:0.87
Viscosity:0.57CP@25C
Evaporation Rate & Reference:1.8 (NBUAC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR WATER-WHITE LIQUID; AROMATIC HYDROCARBON ODOR
Percent Volatiles by Volume:100
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDANTS SUCH AS LIQUID CHLORINE,
CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NOT PROVIDED
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE,
ALDEHYDES AND OTHER DECOMPOSITION PRODUCTS IN THE CASE OF
INCOMPLETE COMBUSTION.

Waste Disposal Methods:NOT PROVIDED

Toxicological Information:THIS PRODUCT HAS A LOW ORDER OF ACUTE ORAL
TOXICITY, BUT MINUTE AMOUNTS ASPIRATED INTO THE LUNGS DURING
INGESTION MAY CAUSE SEVERE PULMONARY INJURY OR DEATH.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED

Transport Information:NOT PROVIDED

SARA Title III Information:NOT PROVIDED
Federal Regulatory Information:NOT PROVIDED
State Regulatory Information:NOT PROVIDED